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Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-symmetrischen Komplexen

Current price: $44.99
Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-symmetrischen Komplexen
Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-symmetrischen Komplexen

Barnes and Noble

Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-symmetrischen Komplexen

Current price: $44.99
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Friederike Adams untersucht 2-Aminoalkoxybis(phenolat)-Lanthanoid-Komplexe in der Seltenerdmetall-katalysierten Gruppentransferpolymerisation von Michael-Monomeren. Neu entwickelte C1-symmetrische Komplexe sind dabei in der Lage, isospezifisch 2-Vinylpyridin zu polymerisieren. Mechanistische Studien über 13C-NMR-Spektroskopie zeigen, dass die Katalysatorumgebung dabei stereoregulierend wirkt. Die Autorin führt außerdem erfolgreich Studien zur C-H-Bindungsaktivierung von Heteroaromaten via σ-Bindungsmetathese durch, um effizientere Initiatoren in diese Systeme einzuführen.

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