The design, -synthesis, and selective pyrolytic conversion of organometallic precursdrs to materials of high purity or specific morphology (for electronic or optical applications), high strength and/or high-temperature stability (for structural or refractory applications) represents a potential area of extreme growth at the overlap of chemistry and materials science (materials chemistry). Research in this area is likely to have considerable impact at both the academic and societal levels because it will require development of scientific expertise in areas currently not well understood. Examples include: (1) The thermodynamics of molecular rearrangements in organometallic molecules at temperatures above 200°C; (2) The electronic properties of amorphous ceramic materials; (3) The phys­ icochemical properties of ceramic molecular composites; and (4) The optical properties of multicomponent glasses made by sol-gel processing. The opportunity to establish the scientific principles needed to pursue useful research goals in "materials chemistry" requires communication between chemists, ceramists, metallurgists, and physicists. To date, there have been few opportunities to create an environment where such communication might occur. The objective of this NATO Advanced Research Workshop was to promote discussions between experts in the varibus disci­ plines aligned with "materials chemistry. " These discussions were intended to identify the scope and potential rewards of research efforts in the development of: Custom-designed precursors to common and exotic materials, methods of selectively transforming these precursors in high yield to the desired material, and methods of characterizing the final products.